Hydrogen sulfide removal by catalytic oxidative absorption method using rotating packed bed reactor

来源 :Chinese Journal of Chemical Engineering | 被引量 : 0次 | 上传用户:lidids
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
Using catalytic oxidative absorption for H_2S removal is of great interest due to its distinct advantages. However,traditional scrubbing process faces a great limitation in the confined space. Therefore, there is an urgent demand to develop high-efficiency process intensification technology for such a system. In this article, H_2S absorption experimental research was conducted in a rotating packed bed(RPB) reactor with ferric chelate absorbent and a mixture of N_2 and H_2S, which was used to simulate natural gas. The effects of absorbent p H value, gas–liquid ratio, gravity level of RPB, absorption temperature and character of the packing on the desulfurization efficiency were investigated. The results showed that H_2S removal efficiency could reach above 99.6% under the most of the experimental condition and above 99.9% under the optimal condition. A long-time continuous experiment was conducted to investigate the stability of the whole process combining absorption and regeneration. The result showed that the process could well realize simultaneous desulfurization and absorbent regeneration, and the H_2S removal efficiency kept relatively stable in the whole duration of 72 h. It can be clearly seen that high gravity technology desulfurization process, which is simple, high-efficiency, and space intensive, has a good prospect for industrial application of H_2S removal in confined space. Using catalytic oxidative absorption for H_2S removal is of great interest due to its distinct advantages. However, there is great interest due to its distinct advantages. However, there is an urgent demand to develop high-efficiency process intensification technology for such a system . In this article, H 2 S absorption experimental research was conducted in a rotating packed bed (RPB) reactor with ferric chelate absorbent and a mixture of N_2 and H_2S, which was used to simulate natural gas. The effects of absorbent p H value, gas- liquid ratio, gravity level of RPB, absorption temperature and character of the packing on the desulfurization efficiency were investigated. The results showed that H2S removal efficiency could reach over 99.6% under the most of the experimental condition and above 99.9% under the optimal condition. A long-time continuous experiment was conducted to investigate the stability of the whole process combining absorption and regeneration. The result showed that the the process did well know simultaneous desulfurization and absorbent regeneration, and the H_2S removal efficiency kept relatively stable in the whole duration of 72 h. It can be clearly seen that high gravity technology desulfurization process, which is simple, high-efficiency , and space intensive, has a good prospect for industrial application of H_2S removal in confined space.
其他文献
经济全球化的深入发展,我国对外开放的逐步扩大,科学技术的提高,以及互联网技术的普及,促使各国之间的交流日益频繁,涉及政治、经济、文化等多个方面.竞争日益激烈的国际环境
When evaluating ionic liquids(ILs) for extractive desulfurization(EDS) of fuel oils, the inevitable presence of water in the system may have a significant and i
期刊
1 玉米种子的收获时期多年生产实践证明,靠自然晾晒降低种子的含水量,确定适宜的收获时期是一项关键性措施。我们曾做过试验,结果是9月15日收获的,虽然收获当时种子含水量达
Aqueous phase of acids as catalysts for the desulfurization of gasoline by condensation of thiophenes with formaldehyde in a biphasic system was investigated. T
两国邦交,世代友好,是各国人民的心愿.如何实现这个心愿,历史那波澜起伏长河告诉我们,最重要的一条,那就是——“布施与感恩常在”.布施,慈善之举,感恩,回报之意,这为世界各
期刊
该文从挂篮荷载计算、施工流程、支座及临时固结施工、挂篮安装及试验、合拢段施工、模板制作安装、钢筋安装、混凝土的浇筑及养生、测量监控等方面人手,介绍了S226海滨大桥
国家技术监督局从1993年开始,每年都对杂交玉米种子质量进行监督检验,结果1993~1995年3a抽检玉米杂交种合格率仅为1.3%~1.6%,纯度在90%以一卜的样品1994年占14.8%,1995年占23.
The application of ionic liquids as alternatives to conventional organic solvents in the extraction process has been investigated. In the present study, fourtee
本试验研究了用能产生2n配子的二倍体杂种作父本,与四倍体栽培种进行杂交以及普通栽培种之间进行杂交其后代在产量上的表现,从而评述了能产生2n配子的二倍体杂交种在马铃薯育