【摘 要】
：
A novel organotin complex [(o-Cl-PhCH2)3SnOCOC10H8N]·0.5C6H6 has been synthesized, and its crystal structure was determined by X-ray diffraction. The crystal b
【机 构】
：
Department of Chemistry and Material Science
【基金项目】
：
湖南省教委科研项目;湖南省自然科学基金
论文部分内容阅读
A novel organotin complex [(o-Cl-PhCH2)3SnOCOC10H8N]·0.5C6H6 has been synthesized, and its crystal structure was determined by X-ray diffraction. The crystal belongs to mo- noclinic, space group C2/c with a = 1.6214(5), b = 1.2033(3), c = 3.2873(10) nm, β = 91.467(5)°, V = 6.411(3) nm3, Mr = 1441.26, Z = 4, Dc = 1.493 g/cm3, ц(MoKα) = 10.79 cm－1, F(000) = 2904, R = 0.0500 and Rw = 0.0884. The bond lengths of Sn-C are 0.2150(5), 0.2157(4) and 0.2164(4) nm, and that of Sn-O is 0.2043(3) nm. The tin atom adopts a distorted tetrahedral geometry.
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