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5. Crystal structure and single crystal EPR of (NH4)2(15-crown-5)3[Cu(mnt)2] and (NH4)2(benzo-15-crown-

Crystal structure and single crystal EPR of (NH4)2(15-crown-5)3[Cu(mnt)2] and (NH4)2(benzo-15-crown-

来源 :中国科学：化学英文版 | 被引量 : 0次 | 上传用户：zy198187

【摘 要】

：

The X-ray crystal structures of (NH4)2(15-crown-5)3[Cu(mnt)2] (1) and (NH4)2(benzo-15-crown-5)4- [Cu(mnt)2]·0.5H2O (2) were determined. Two single crystals

【作 者】

：

SUI YunXia WEN LiLi ZHANG Huan 

【机 构】

：

CenterofModernAnalysis

【出 处】

：

中国科学：化学英文版

【发表日期】

：

2007年5期

【关键词】

：

supramolecular cation H-BONDING interaction EPR g and A tensors DFT supramol 

【基金项目】

：

Supported by the National Natural Science Foundation of China (Grant No. 20490218)

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The X-ray crystal structures of (NH4)2(15-crown-5)3[Cu(mnt)2] (1) and (NH4)2(benzo-15-crown-5)4- [Cu(mnt)2]·0.5H2O (2) were determined. Two single crystals are composed of distinct structures of ammonium-crown ether supramolecular cation and [Cu(mnt)

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