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用压淬的方法,在6GPa静高压下,以200K/s的冷却速率冷却熔融状态的Cu_(70)Si_(30)合金,制备出块状Cu-Si纳米合金.X射线衍射和透射电子显微镜分析表明:该纳米合金由γ-Cu_5Si和一未知相组成,未知相为简单立方晶体,晶格常数α=0.8535nm,其热力学状态为亚稳态。并对静高压下块状纳米合金的形成机理进行了探讨。
The Cu-Si nanostructures were prepared by pressure-quenching the molten Cu 70 Si 30 alloy under a static pressure of 6 GPa at a cooling rate of 200 K / s. The results of X-ray diffraction and transmission electron microscopy show that the nanocrystalline alloy consists of γ-Cu_5Si and an unknown phase. The unknown phase is a simple cubic crystal with a lattice constant α = 0.8535 nm. The thermodynamic state is metastable state. The formation mechanism of massive nanostructures under static pressure was also discussed.