用热力学 /超热力学方法对杯 [4]芳烃衍生物气相色谱固定相上芳烃位置异构体的分离进行了研究。考察了一系列芳烃位置异构体在杯芳烃色谱柱上分离过程的热力学参数及其选择性之间的关系 ,并对杯 [4]芳烃衍生物气相色谱固定相分离芳烃位置异构体的保留机理进行了探讨 Thermodynamics / hyperthermodynamics was used to study the separation of aromatic isomers on the stationary phase of calix [4] arene derivatives. The relationship between the thermodynamic parameters and the selectivity of a series of isomers of isomers of aromatic hydrocarbons on the separation process of calixarene were investigated and the retention of the isomers of aromatic isomers of the calix [4] arene derivatives by GC Mechanism is discussed