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在乙醇溶剂中冰醋酸催化下,2-羟基-5-叔丁基-1,3-亚苯基二甲醛和相应的取代苯胺缩合得到74.6%～85.7%的双席夫碱配体.将配体分别与CoCl2@6H2O和NiCl2@6H2O反应,得到6个配合物,收率74.1%～85.2%.合成路线简单易行,产率高.“,”The 2,6 - bis(imino) phenoxy ligands were prepared in 74.6 % ～ 85.7 % yield by the condensa-tion of the appropriate aniline with 2 - hydroxy - 5 - tert - butyl - isophthaldehyde. A series of new cobalt andnickel complexes LMX2(M = Co, X = Cl; M = Ni, X= Cl) bearing 2,6 - bis(imino)phenoxy ligands were syn-thesized in yield 74.1% ～ 85.2 %.