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本文基于负离子配位多面体生长基元模型，分析确定了两种晶型锑白的不同结构基元：ＳｂＯ_３配位四面体与ＳｂＯ_３＋３Ｅ星状四面体；详细探讨了水解法制锑白时水解介质等条件对其晶型结构影响的机理，得到了水解法制锑白时控制晶型结构的规律．
In this paper, different structural motifs of SbO_3 coordination tetrahedrons and SbO_3 + 3E star tetrahedra were analyzed based on the elementary model of polyanion coordinated growth of anion. The conditions of hydrolysis medium such as antimony white were studied in detail The mechanism of the influence on its crystal structure was obtained by the hydrolysis of antimony white crystal structure control law.