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A new mononuclear copper (Ⅱ) complex, [Cu(dbpy)2Cl]-OH·0.5CH3OH·2H2O(dbpy=4,4′-dimethyl-2,2′-bipyridine) (C24.50H31ClCuN4O3.50, Mr=536.52) has been synthesized and its crystal structure was determined by X-ray diffraction method. It crystallizes