【摘 要】
：
A hyperbranched poly(aryleneethynylene) containing anthracene chromophore was synthesized by palladiumcatalyzed cross-coupling reaction of 2,4,6-triiodophenyl 9
【机 构】
：
Department of Polymer Science and Engineering,Department of Chemistry
【基金项目】
：
the Research Grants Council of Hong Kong Special Administrative Region, China;the University Grants Committee of Hong Kong via an Area of Excellence (AoE) Scheme
论文部分内容阅读
A hyperbranched poly(aryleneethynylene) containing anthracene chromophore was synthesized by palladiumcatalyzed cross-coupling reaction of 2,4,6-triiodophenyl 9-anthracenylcarboxylate with 9,9-bis[4-(2-propynyloxy)phenyl]-9H-fluorene. The structure and properties of the polymer are characterized and evaluated by NMR, IR, UV, PL and TGA analyses. The polymer is soluble in common organic solvents, possesses high thermal stability (Td ＞ 330℃), and emits a strong blue light of 465 nm in both solution and solid states.
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