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  5. An Efficient Synthesis of Tertiaryaminomethylphosphonates, A Versatile Precursor for Synthesis of Gl

An Efficient Synthesis of Tertiaryaminomethylphosphonates, A Versatile Precursor for Synthesis of Gl

来源 :中国化学快报 | 被引量 : 0次 | 上传用户：eternaty
【摘 要】
：
Reaction of simple dialkyl phosphites with symmetrical 1,3,5-trisubstituted hexahydro- triazines (HHTs) in the presence of benzyl chloride, afforded tertiaryami
【作 者】
：
Liang XU Min XIA Jun Chao CAI 
【机 构】
：
Shanghai Institute of Materia Medica
【出 处】
：
中国化学快报
【发表日期】
：
2004年期
【关键词】
：
Glyphosate α-aminomethylphosphonate 1 3 5-hexahydrotriazine dialkylphosphite 
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Reaction of simple dialkyl phosphites with symmetrical 1,3,5-trisubstituted hexahydro- triazines (HHTs) in the presence of benzyl chloride, afforded tertiaryaminomethylphosphonates in excellent yields. Glyphosate, α-aminomethylphosphonates and their derivatives can therefore be synthesized by this procedure conveniently.
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