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A new bicadmium(??) complex [Cd2L](ClO4)2?1.25H2O (C28H35Cd2Cl4N6O13.25) was synthesized and characterized by X-ray diffraction and ES mass spectral analyses. It crystallizes in the triclinic system, space group P1 with a = 15.630(3), b = 15.990(3), c = 16.330(3) ?, α = 89.90(3), β = 68.87(3), γ = 87.94(3)o, V = 3804.1(13) ?3, Mr = 1034.22, Z = 4, F(000) = 2060, Dc = 1.806 g/cm3, T = 293(2) K, μ = 1.468 mm-1 and λ = 0.71073 ?. The structure was refined to R = 0.0779 and wR = 0.1960 for 7034 observed reflections with I > 2σ(I).
A new bicadmium (?) Complex [Cd2L] (ClO4) 2? 1.25H2O (C28H35Cd2Cl4N6O13.25) was synthesized and characterized by X-ray diffraction and ES mass spectral analyzes. It crystallizes in the triclinic system, space group P1 with a Α = 89.90 (3), β = 68.87 (3), γ = 87.94 (3) o, V = 3804.1 (13)? 15.630 (3) b = 15.990 c = 16.330? 3, Mr = 1034.22, Z = 4, F (000) = 2060, Dc = 1.806 g / cm3, T = 293 (2) K, μ = 1.468 mm-1 and λ = 0.71073. = 0.0779 and wR = 0.1960 for 7034 observed reflections with I> 2σ (I).