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The metal-organic framework(MOF){[Cu(L1)_(0.5)(CN)]·4H_2O·3DMSO}_n(1) was assembled by 1,4-bis(3?,5?-dicyano-2?,6?-di(pyrid-4-yl)-1?,4?-dihydropyridyl)benzene(L1) together with copper cyanide at room temperature. In 1,the Cu~+ ions are linked by