论文部分内容阅读
烯烃的催化氢化为烯烃向烷烃的转化提供了最具有原子经济性的途径.目前,用于烯烃氢化的催化剂主要为过渡金属化合物,而开发低毒高效的非金属烯烃氢化催化剂正在吸引越来越多的关注.其中非官能团化的烯烃的非金属催化氢化,是一项非常具有挑战性的课题.复旦大学化学系王华冬课题组发现以具有强Lewis酸性的硼氢化合物HB(C6F5)2为催化剂,可以成功地实现一系列非官能团化的烯烃的催化氢化反应.动力学实验及密度
Catalytic hydrogenation of olefins provides the most atomically economical route to the conversion of olefins to alkanes. Currently, the catalysts used for the hydrogenation of olefins are predominantly transition metal compounds and the development of less toxic and efficient non-metal olefin hydrogenation catalysts is attracting more and more More attention.And non-functionalized olefin non-metallic catalytic hydrogenation, is a very challenging topic.Fudan University Department of Chemistry Wang Hua-dong research group found that the strong Lewis acid boric acid HB (C6F5) 2 as a catalyst , A series of non-functionalized olefins can be successfully catalyzed hydrogenation reaction kinetic experiments and density