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Two one-dimensional chain-like cyanide-bridged compounds, [Fe(Phen)2(CN)2Ni-(Cyclam)](ClO4)2·DMF·2H2O 1 (Cyclam = 1,4,8,11-tetraaza-cyclotetradecane, Phen = 1,10-phenan-throline, and DMF = N,N-dimethylformamide) and [Fe(Phen)2(CN)2Zn(Cyclam)](PF