Perovskite-type Ba0.5Sr0.5Co0.8Fe0.2O3-δ (BSCFO) powders were synthesized using two methods, solid-state reaction (SSR) method and cit-rate-EDTA complexing method (CC-EDTA). Then the powders were pressed to green disks of 19 mm in diameter and sintered at 1140℃ for 5 h. The shrinkage rate and relative density of the membranes prepared from the perovskite-type powders were determined and calculated, and the powders and derived membranes were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The re-sults show that the shrinkage rates of the two kinds of disks are nearly the same (about 10%). The disks prepared by the SSR method had a bigger grain size and lower relative density than those prepared by the CC-EDTA method. The conductivity of the membranes prepared by the SSR method was about 38 S/cm, higher than that of the membranes prepared by the CC-EDTA method, which was about 30 S/cm, at the same temperature of 600℃.