【摘 要】
：
The title compound, (H2en) 3H3O { MosV4O36 (VO4) (VO) 2 } · 4H2O, was hydrothermally synthesized and structurally characterized by means of IR, ESR spectrum an
【机 构】
：
Department of Chemistry,Changchun Institute of Applied Chemistry
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The title compound, (H2en) 3H3O { MosV4O36 (VO4) (VO) 2 } · 4H2O, was hydrothermally synthesized and structurally characterized by means of IR, ESR spectrum and single crystal X-ray diffraction. It crystallized in a monoclinic system with space group P21/c, a= 1. 980 4(4)nm, b＝2. 063 4(4) nm, c=1. 192 0(2) nm, β=94. 76(3)°and deep black colour. The compound contains V-centered bi-capped a-Keggin fragments { MosV7O42 } that are linked together by edge-shared units V ⅣO5 via V-O-V bonds, forming a chain.
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