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利用Ph3SnCl与N-亚水杨酰基-4-氨基苯甲酸以1∶1摩尔比反应,合成了Ph3Sn(OOCC6H4NCHC6H4OH-2).用X-射线单晶衍射测定了该配合物的晶体结构,结果表明,在该配合物的晶体中,锡原子呈五配位畸变三角双锥构型.
Ph3Sn (OOCC6H4NCHC6H4OH-2) was synthesized by the reaction of Ph3SnCl with N-salicyloyl-4-aminobenzoic acid in a molar ratio of 1: 1. The crystal structure of the complex was determined by X-ray single crystal diffraction. In the crystal of the complex, the tin atom presents a five-coordinate distorted triangular double cone configuration.