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致密、纯钙钛矿结构的PZT(50/50)铁电薄膜已用MOD工艺(金属有机物热分解工艺)获得.通过优化原料的提纯和合成工艺,消除了原料中微量杂质离子,控制PZT先体溶液合成时的环境温度,制得透明、稳定的锆钛酸铅先体溶液.采用多次甩胶成膜法,经400~500℃热处理,在Pt/SiO2/Si衬底上制得PZT(50/50)薄膜,膜厚520nm,其介电常数为270,损耗角正切为0.035(1kHz,0.05V测试电压),其绝缘电阻率为10~100TΩ·cm,剩余极化强度为20.6μC/cm2,饱和极化强度为27.7μC/cm2,矫顽场强为80kV/cm
The dense, pure perovskite PZT (50/50) ferroelectric thin film has been obtained using the MOD process (metal-organic thermal decomposition process). By optimizing the purification and synthesis of raw materials, the trace impurity ions in the raw materials are eliminated and the ambient temperature during the synthesis of PZT precursor solution is controlled to obtain a transparent and stable lead zirconate titanate precursor solution. PZT (50/50) thin film was prepared on Pt / SiO2 / Si substrate by heat-treatment at 400-500 ℃ for several times. The dielectric constant was 270 and the loss tangent was 0.035 (1kHz, 0.05V test voltage), the insulation resistivity of 10 ~ 100TΩ · cm, the remanent polarization of 20.6μC / cm2, the saturation polarization of 27.7μC / cm2, coercive field strength 80kV / cm