【摘 要】
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Monodisperse functional polymer microspheres with different particle size and with clean surface were prepared by batch soap-free emulsion polymerization of sty
【机 构】
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Department of Chemical Engineering and Key Laboratory of Advanced Materials of Ministry of Education
论文部分内容阅读
Monodisperse functional polymer microspheres with different particle size and with clean surface were prepared by batch soap-free emulsion polymerization of styrene, methyl methacrylate and acrylic acid in the presence of salts, and the influences of type and amount of electrolytes on polymerization process and particle morphology were investigated. Results showed that there was a critical concentration for different electrolyte to make polymerization process and the resultant emulsion stable, and the particle size increased with the increase of electrolyte concentration. The effect of metal ions was Ca2+>>K+>Na+>Li+, and the effect of haloids was Br->Cl->F-.
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