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以高氯酸锌、1,2-丙二胺(1,2-pn)为原料在甲醇介质中反应,合成得到了新颖单核锌配合物[Zn(1,2-pn)3](ClO4)2,用元素分析、IR、1HNMR和热重分析等手段对该化合物的结构进行了表征,并用单晶X-射线衍射法测得其晶体结构为单斜晶系,空间点群为C2/c,晶体学参数为:a=2.971 4(11)nm,b=0.978 0(4)nm,c=1.780 3(5)nm,α=90.00°,β=122.90(2)°,γ=90.00°,V=4.344(3)nm3,Dc=1.488 g/cm3,Z=8,F(000)=2 032,μ=1.421 mm-1。
A novel mononuclear zinc complex [Zn (1,2-pn) 3] (ClO4) was synthesized by the reaction of zinc perchlorate and 1,2-propanediamine in methanol. ) 2. The structure of the compound has been characterized by elemental analysis, IR, 1HNMR and TG analysis. The crystal structure of the compound is monoclinic by single crystal X-ray diffraction. The point group of space is C2 / The crystallographic parameters are: a = 2.971 4 (11) nm, b = 0.978 0 (4) nm, c = 1.780 3 (5) nm, α = 90.00 °, β = 122.90 (2) °, °, V = 4.344 (3) nm3, Dc = 1.488 g / cm3, Z = 8, F (000) = 2 032, μ = 1.421 mm-1.