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Titanium phosphonate adsorbent materials with hierarchically porous structure were fabricated using the hydrolysis of tetrabutyl titanate in different organophosphonic acids solutions. Based on the macroporous structure of 100-2000 nm in size, a worm-hole like mesostructure was in the macropore walls, which was supported by the scanning electron microscopy(SEM), transmission electron microscopy(TEM), and N_2 sorption analysis. Fourier transform infrared spectroscopy(FT-IR) data indicated the organic groups inside the solid materials framework. NH_3 adsorption detection was performed using titanium phosphonate adsorbent materials and some significant results were obtained. The adsorption mechanism was also discussed in this study. Large adsorption amount(75.2 mg/g) was mainly attributed to the acid site via acid-base reactions and the physical adsorption site via Van der Waals forces. Resultant materials could effectively restrain the desorption of adsorbent NH_3 back into air causing secondary pollution, so it could make a promising potential use in decontamination of gas pollutants in the future.
Titanium phosphonate adsorbent materials with hierarchically porous structure were fabricated using the hydrolysis of tetrabutyl titanate in different organophosphonic acids solutions. Based on the macroporous structure of 100-2000 nm in size, a worm-hole like mesostructure was in the macropore walls, which was supported by scanning electron microscopy (SEM), transmission electron microscopy (TEM), and N_2 sorption analysis. Fourier transform infrared spectroscopy (FT-IR) data indicated the organic groups inside the solid materials framework. NH_3 adsorption detection was performed using titanium phosphonate adsorbent The adsorption mechanism was also discussed in this study. Large adsorption amount (75.2 mg / g) was mainly attributed to the acid site via acid-base reactions and the physical adsorption site via Van der Waals forces. Resultant materials could effectively restrain the desorption of adsorbent NH3 back into air causing s econdary pollution, so it could make a promising potential use in decontamination of gas pollutants in the future.