Ni-Ga alloy(Ni/Ga atomic ratio of 8),Ni3Ga and Ni5Ga3 intermetallic compounds(IMCs)catalysts were prepared from Ni-Mg-Al-Ga layered double hydroxides(LDHs)for the deoxygenation of methyl esters to hydrocarbons.In the alloy and IMCs,the presence of Ga reduced the surface Ni atom density,and the charge transfer from Ga to Ni increased the electron density of Ni.In the deoxygenation of methyl lau-rate,the Ni catalyst gave a complete hydrogenolysis of methyl laurate to CH4 at 330℃and 3.0 MPa,while the presence of Ga promoted the HDO pathway and suppressed C-C bond hydrogenolysis and methana-tion.The Ni5Ga3 catalyst exhibited the best desired performance.Even at 400℃,it gave the yield of C11 and C12 hydrocarbons of～99％,and the selectivity to CH4(ScH4)was only 2.4％.In the deoxygenation of methyl octanoate and methyl palmitate,the Ni5Ga3 catalyst also gave the yield of hydrocarbons above 95％.Reactivity evaluation and methyl propionate-TPD and TPSR results indicate that the C-OCH3 bond instead of the O-CH3 one was cleaved on both Ni and bimetallic Ni-Ga catalysts.It is highlighted that methanol,derived from the C-OCH3 bond hydrogenolysis,mainly decomposed to CO and H2 on IMCs,while it was converted to methane on metallic Ni and alloy.It is of great significance that H2 could be yielded from the methyl ester itself.In short,the utilization of Ni-Ga IMCs can effectively reduce carbon loss and H2 consumption.all of which are ascribed to the geometric and electronic effects of Ga.