The precipitation processes of γand θ phases in Ni75 Al6.5 V18.5 alloy were simulated at different temperatures and the precipitation sequence of two phases and morphological evolution were investigated.The simulation demonstrates that the two phases precipitate simultaneously at high temperature and γphase precipitates earlier than θ phase at 1 000 K and 1 120 K.With the temperature decreasing,the velocity of precipitation quickens,the quantity of θ phase increases and the size reduces;but the volume fraction increases,the quantity of phase increases and the size reduces as well.The two phases nucleate and grow independently at high temperature and the θ phase precipitates from the boundaries of γphase at 1 000 K and 1 120 K.We also find that there are many kinds of domain boundaries between the same and different phases.The results of average deviation of composition and average absolute long range order parameter show that the ordering and compositional clustering of γphase happen simultaneously at high temperature,the congruent ordering occurs prior to spinodal decomposition at 1 000 K and 1 120 K and the ordering advances and quickens as the temperature decreases.Ordering and compositional clustering of θphase occur simultaneously at each temperature and are quickened with temperature decreasing.