四氮唑及其衍生物,由于其具有较多的配位点和灵活的配位模式而被广泛关注。对5-取代四氮唑配体研究的比较多,并得到了许多结构新颖的功能配位聚合物,而1-取代四氮唑的配合物研究的相对较少,仅有一些低维配合物已被报道。本文合成了一个不对称的有机配体:1-(1H-苯并咪唑基-2-甲基)-1,2,3,4-四氮唑(Hbimtz),初步探讨了它和金属隔离子的配位化学反应。 Tetrazole and its derivatives, due to its more coordination points and flexible coordination mode has been widely concerned. There are many studies on 5-substituted tetrazolium ligands, and many novel functional coordination polymers have been obtained. However, relatively few complexes of 1-substituted tetrazolium have been studied, only some low dimensional complexes Has been reported. In this paper, an asymmetric organic ligand, Hbimtz, was synthesized and its interaction with metal spacer Coordination chemical reaction.