【摘 要】
：
In persulfate-acetate, dimethyl sulfoxide or tert-butyl alcohol systems, in situ generation and detection of methyl free radical are realized with voltammetry.
【机 构】
：
Institute of Analytical Science,Department of Chemistry
【基金项目】
：
国家自然科学基金;陕西省自然科学基金
论文部分内容阅读
In persulfate-acetate, dimethyl sulfoxide or tert-butyl alcohol systems, in situ generation and detection of methyl free radical are realized with voltammetry. It includes the following successive processes. The persulfate S2O82- is polarographically reduced via one-electron addition to sulfate radical SO4-., the SO4-. Initiates chain reaction with acetate, dimethyl sulfoxide, or tert-butyl alcohol on the electrode surface to produce a methyl radical, and one-electron reduction of the methyl radical yields its polarographic reduction wave. In comparison with the known techniques such as ultraviolet radiolysis coupling with electron spin resonance, etc., the proposed method is simple, sensitive and selective.
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