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The title compound was obtained by reaction of CoCl2.6H2O and mp2- (σ-C6H4SO2-) in MeCN,crystallized as Et4N+ salt in monoclinic system with space group P21/c, Mr=877.040. The cell parameters are:a =16.606(2), b=15.575(1),c=17.725(2)A,β=111.07(1)°,V=4277.8A3,Z=4,Dx= 1.36g/cm3.It is a dimer of [Co(mp)(Hmp)]- connected by two strong hydrogen bonds with a twist angle of about 36.94 .
The title compound was obtained by reaction of CoCl2.6H2O and mp2- (σ-C6H4SO2-) in MeCN, crystallized as Et4N + salt in monoclinic system with space group P21 / c, Mr = 877.040. The cell parameters are: a = 16.606 (2), b = 15.575 (1), c = 17.725 (2) A, β = 111.07 (1) °, V = 4277.8A3, Z = 4 and Dx = 1.36 g / cm3.It is a dimer of [Co ( mp) (Hmp)] - connected by two strong hydrogen bonds with a twist angle of about 36.94.