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根据热动力学基本理论,推导了对峙反应的热动力学对比参量方程,建立了对峙反应对比参量法的数学模型.该法利用特征时间tm和2tm时对应的热谱数据计算反应的对比参量,进而解析出较慢对峙反应的速率常数和平衡常数.利用该法分别研究了硝基乙烷与氨和三（羟甲基）氨基甲烷质子转移反应的热动力学,实验结果表明了较慢对峙反应对比参量法的正确性.
According to the basic theory of thermodynamics, the thermodynamic parameters of the reaction are deduced, and the mathematical model of the confrontation reaction parameter method is established.The corresponding parameters of the reaction are calculated by using the corresponding time series data of tm and 2tm, Then the rate constants and the equilibrium constants of the reaction were also analyzed.The thermodynamics of the proton transfer reaction between nitroethane and ammonia and tris (hydroxymethyl) aminomethane were studied by using this method respectively. The experimental results showed that the slow reaction The correctness of the comparative parametric method.