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利用5-磺酸基间苯二甲酸钠(Na H2sip)和双三唑烷烃,合成了3个配合物[Cu0.5(btm)(H2O)](H2sip)·H2O}n(1,btm=双三唑甲烷),{[Cu(btp)2(H2sip)(H2O)](NO3)·4H2O}n(2,btp=双三唑丙烷)和{[Cu(btb)2(Hsip)]n(3,btb=双三唑丁烷)。化合物1为一维双链结构;化合物2为二维四方网络结构,多个二维层依次叠加形成三维超分子结构;化合物3也具有二维层状结构,其中金属铜离子和双三唑丁烷构成的一维双链结构经双齿μ2-Hsip2-配体连接构成了二维层状结构。同时对配合物的热稳定性和顺磁共振特性进行了讨论。
Three complexes [Cu0.5 (btm) (H2O)] (H2sip) · H2O} n (1, btm = Triazoles), {[Cu (btp) 2 (H 2 sip) (H 2 O)] (NO 3) · 4H 2 O} n (2, btp = 3, btb = bis-triazole butane). Compound 1 is a one-dimensional double-stranded structure; compound 2 is a two-dimensional tetragonal network structure, and a plurality of two-dimensional layers are sequentially stacked to form a three-dimensional supramolecular structure; and compound 3 also has a two-dimensional layered structure in which copper ions and bis The one-dimensional double-stranded structure of alkyl forms a two-dimensional layered structure through bidentate μ2-Hsip2-ligand connection. The thermal stability and paramagnetic resonance properties of the complexes were also discussed.