Closed and endoreversible chemical oscillation

来源 :Chinese Journal of Chemistry | 被引量 : 0次 | 上传用户:shixibaogao007
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Based on a simple nonideal chemical reaction model, the closed system with reversible nonideal reactions and illumination is shown to be able to exhibit sustained oscillation. The essential points in the occurrence of such oscillations are the nonideality of reacting media, which gives rise to multiple chemical equilibria, and the energy flow through illumination and heat conduction, which gives rise to spontaneous transitions repeatedly between the multiple equilibrium states. During the oscillation, reacting media undergo only reversible chemical transformation and all irreversibilities are restricted to the coupling of the system to external world. This oscillation provides an example of the so-called endoreversible machine and a possible way to convert radiation energy of the light directly into mechanical energy. Based on a simple nonideal chemical reaction model, the closed system with reversible nonideal reactions and illumination is shown non-manifestative sustained oscillation. The essential points in the occurrence of such oscillations are the nonideality of reacting media, which gives rise to multiple chemical equilibria, and the energy flow through illumination and heat conduction, which gives rise to spontaneous transitions repeatedly between the multiple equilibrium states; during the oscillating, reacting media undergo only reversible chemical transformation and all irreversibilities are restricted to the coupling of the system to the external world . This oscillation provides an example of the so-called endoreversible machine and a possible way to convert radiation energy of the light directly into mechanical energy.
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