【摘 要】
：
The title compounds have been respectively synthesized by solution process and solvothermal reaction, and their crystal structures were determined by X-ray diff
【机 构】
：
Chemistry and Life Science School,State Key Laboratory of Structural Chemistry
【基金项目】
：
福建省自然科学基金;NSF for Young Scientist of CAS. Electronic supplementary information (ESI)
论文部分内容阅读
The title compounds have been respectively synthesized by solution process and solvothermal reaction, and their crystal structures were determined by X-ray diffraction method. For (CH3CH2CH2CH2NH3)6(BiI6)(I)2I3 1, it crystallizes in triclinic, space group P with Mr = 2049.76, a = 8.5719(1), b = 11.7461(3), c = 15.700(1) ?, V = 1451.4(1) ?3, Z = 1, Dc = 2.345 g/cm3, F(000) = 924, ((MoK() = 8.907 mm-1, T = 293(2) K, the final R = 0.0655 and wR = 0.0804 for 2399 observed reflections with I > 2((I). For (NH3CH2CH2NH3)2Bi2I10 2, it crystallizes in monoclinic, space group P21/n with Mr = 1811.20, a = 8.434(4), b = 13.862(6), c = 13.362(6) ?, V = 1499.9(12) ?3, Z = 2, Dc = 4.010 g/cm3, F(000) = 1536, ((MoK() = 22.007 mm-1, T = 293(2) K, the final R = 0.0584 and wR = 0.1451 for 1798 observed reflections with I > 2((I). The structures of 1 and 2 contain halobismuthate monomer and dimers, respectively. It is noteworthy that the dimers and their organic counters in 2 connect each other by N
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