论文部分内容阅读
The title complex Cu[C5H3N(CCH3=N-C6H5)2]2(PF6)2 has been synthesized by r eaction of Schiff base C5H3N(CCH3=N-C6H5)2 and cupric sulfate in toluene solut ion. The crystal structure was determined by X-ray diffraction method and the chemical formula weight of the complex is 1041.85. The crystal structure belongs to triclinic system with spacegroup and cell parameters: a=12.6470(10) , b=14. 123(2) , c=15.613(2);á=66.150(10)a=79.470(10)?=78.290(10)穖-3 and F(000)=1064. The final R:R1=0.0668, wR 2=0.1927; R(all data): R1=0.1133, wR2=0.2357. The Cu was coordinated by six nitrogen, at the same time the Cu formed a distorted octahedron, besides the angles and pl anes of this compound were discussed . The result of kinetics of the thermal dec omposition indicated that the first step of it is 2 series chemical reactions, t he function of machanism is f(a)=(1-a)2, and the activation energy is 144.64E/ kJ. CCDC: 180872.
The title complex Cu [C5H3N (CCH3 = N-C6H5) 2] 2 (PF6) 2 has been synthesized by the reaction of Schiff base C5H3N (CCH3 = N-C6H5) 2 and cupric sulfate in toluene determined by X-ray diffraction method and the chemical formula weight of the complex is 1041.85. The crystal structure belongs to triclinic system with spacegroup and cell parameters: a = 12.6470 (10), b = 14.123 (2), c = 15.613 (2); á = 66.150 a = 79.470 (10)? = 78.290 (10) 穖 -3 and F (000) = 1064. The final R: R1 = 0.0668, wR2 = 0.1927; ): R1 = 0.1133, wR2 = 0.2357. The Cu was coordinated by six nitrogen, at the same time the Cu formed a distorted octahedron, besides the angles and pl anes of this compound were discussed. The result of kinetics of the thermal decoupling indicated that the first step of it is 2 series chemical reactions, t he function of machanism is f (a) = (1-a) 2, and the activation energy is 144.64E / kJ. CCDC: 180872.