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A cyano-bridged heterometallic supramolecular complex {[Cu(pn)]3[Ni(CN)4]3}n (1) has been synthesized and structurally characterized by single crystal X-ray diffraction. 1 displays an interesting 3D structure formed by μ4, μ3-[Ni(CN)4]2- tectons bridging five-coordinated and six-coordinated Cu(Ⅱ) ions. The magnetic property shows that 1 behaves as weakly ferromagnetic interactions between the adjacent Cu(Ⅱ) ions through the diamagnetic spacer NC-Ni-CN. CCDC: 624387.
A cyano-bridged heterometallic supramolecular complex {[Cu (pn)] 3 [Ni (CN) 4] 3} n (1) has been synthesized and structurally characterized by single crystal X-ray diffraction. The magnetic property shows that 1 behaves as weakly ferromagnetic interactions between the adjacent Cu (II) ions through the diamagnetic spacer NC-Ni-CN. CCDC: 624387.