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Kolbe反应距今已有一百余年,但在许多有机化合物的合成中仍占有重要地位。我们在用长链羧酸通过Kolbe反应合成一些高级烷烃的实验中,曾遇到一些困难:由于反应原料是长链羧酸和它的盐,因此大多数电解液是由水、醇等极性溶剂组成。而阳极氧
Kolbe reaction has been more than one hundred years ago, but still plays an important role in the synthesis of many organic compounds. We have encountered some difficulties in the synthesis of some higher alkanes by the Kolbe reaction with long chain carboxylic acids: Since the starting material is a long chain carboxylic acid and its salts, most of the electrolyte is composed of water, alcohol and other polar Solvent composition. Anode oxygen