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研究了一系列具有很强非晶形成能力（ＧＦＡ）和优异性能的块体金属玻璃（ＢＭＧ）及含有纳米晶的 ＢＭＧ的制备过程，结果表明，对掺碳的 Ｚｒ／Ｔｉ基 ＢＭＧ，当碳含量（原子分数，％，下同）在 １—２时，合金具有很宽的过冷液相区（ＳＬＲ，晶化开始温度 Ｔｘ和玻璃转变温度 Ｔｇ之间的温区）和较高的约化玻璃转变温度 Ｔｒｇ（Ｔｒｇ－ Ｔｇ／Ｔｍ）；当碳含量增至 ３—８时，合金为含有纳米晶 ＺｒＣ的 ＢＭＧ基复合材料加 Ｆｅ的 Ｚｒ／Ｔｉ基 ＢＭＧ的 Ｆｅ含量最高可以达到 ８，当 Ｆｅ含量为 １０—１５时得到的是含有纳米晶 Ｚｒ２Ｆｅ的 ＢＭＧ材料． Ｚｒ／Ｎｂ基 ＢＭＧ的 ＧＦＡ和 Ｚｒ／Ｔｉ基 ＢＭＧ的 ＧＦＡ相当，但是 Ｔｇ和 Ｔｘ更高，因此具有更好的热稳定性．含 Ｆｅ的 Ｚｒ／Ｎｂ基 ＢＭＧ在 Ｆｅ含量为 ８时具有最高的 ＧＦＡ． Ｚｒ／Ｔｉ基 ＢＭＧ中掺入 Ｙ，可使其 Ｙｏｕｎｇ’ｓ模量、切变模量高于其他 Ｚｒ基 ＢＭＧ的相应模量
A series of preparation processes of bulk metallic glass (BMG) and nanocrystalline BMG with strong amorphous formation ability (GFA) and excellent properties were studied. The results show that for carbon-doped Zr / Ti-based BMG, Content (atomic fraction,%, the same below) at 1-2, the alloy has a very wide supercooled liquid region (SLR, crystallization start temperature Tx and the glass transition temperature Tg between) and higher about When the carbon content is increased from 3 to 8, the content of Fe in the Zr / Ti-based BMG with BMG-based composite containing nanocrystalline ZrC and Fe is up to 8, When the Fe content is 10-15, a BMG material containing nanocrystalline Zr2Fe is obtained. The GFA of the Zr / Nb-based BMG is comparable to the GFA of the Zr / Ti-based BMG, but has a higher Tg and Tx and hence better thermal stability. The Fe-containing Zr / Nb-based BMG has the highest GFA at a Fe content of 8. Incorporation of Y into the Zr / Ti-based BMG allows its Young’s modulus, which is higher than that of other Zr-based BMGs