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The ground state geometries, frontier molecular orbital properties, and absorption properties of 4,4′-(ethane-1,2-diylbis(oxy))dibenzaldehyde (EDO-DBDHD) and its polymorph have been studied theoretically. The density functional theory (DFT) method was employed to optimize the ground state geometries, and theoretical data reveal that EDO-DBDHD features the planar molecular conformations, in contrast to V-shaped structures of its polymorph, which agrees with the experimental data. Additionally, the absorption spectra of both compounds were predicted using time-dependent density functional theory (TDDFT). The calculated results show that the lowest lying absorption bands of these compounds have the transition configurations of HOMO → LUMO, resulting in the transition character of π→π*/n→π*. The transition of HOMO → LUMO+3 mainly contributes to the highest lying absorption bands of two compounds at 225 nm with the character of π→π*/n→π*.
The ground state geometries, frontier molecular orbital properties, and absorption properties of 4,4 ’- (ethane-1,2-diylbis (oxy)) dibenzaldehyde (EDO- DBDHD) and its polymorph have been studied theoretically. DFT) was employed to optimize the ground state geometries, and theoretical data reveal that EDO-DBDHD features the planar molecular conformations, in contrast to V-shaped structures of its polymorph, which agrees with the experimental data. Both compounds were predicted using time-dependent density functional theory (TDDFT). The calculated results show that the lowest absorption bands of these compounds have the transition configurations of HOMO → LUMO, resulting in the transition character of π → π * / n → π *. The transition of HOMO → LUMO + 3 mainly contributes to the highest absorption bands of two compounds at 225 nm with the character of π → π * / n → π *.