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A new phosphovanadate metal-organic complex Cu(mbpy)(VO_2)(PO_4)(1, mbpy = 5,5?-dimethyl-2,2?-dipyridyl) has been hydrothermally synthesized and structurally characterized. Single-crystal structure analysis reveals that compound 1 crystallizes in the monoclinic space group P21/c with a = 7.6640(4), b = 18.8832(10), c = 10.1893(5) ?, β = 94.782(1)o, V = 1469.47(13) ?3, Z = 4, Mr = 425.69, Dc = 1.924 g/cm~3, F(000) = 852, μ(Mo Kα) = 2.224 mm-1, R = 0.0291 and w R = 0.0980. The crystal structure of 1 features a one-dimensional framework constructed by inorganic {Cu(VO_2)(PO_4)}∞ neutral chain and organic mbpy ligands. The electrochemical property of compound 1 modified carbon paste electrode has also been investigated.
A new phosphovanadate metal-organic complex Cu (mbpy) (VO_2) (PO_4) (1, mbpy = 5,5 -dimethyl-2,2 -dipyridyl) has been hydrothermally synthesized and structurally characterized. that compound 1 crystallizes in the monoclinic space group P21 / c with a = 7.6640 (4), b = 18.8832 (10), c = 10.1893 (5) ?,? = 94.782 (1) o, V = 1469.47 3, Z = 4, Mr = 425.69, Dc = 1.924 g / cm ~ 3, F (000) = 852, Mo (Kα) = 2.224 mm-1, R = 0.0291 and w R = 0.0980. 1 features a one-dimensional framework constructed by inorganic {Cu (VO_2) (PO_4)} ∞ neutral chain and organic mbpy ligands. The electrochemical property of compound 1 modified carbon paste electrode has also been investigated.