【摘 要】
:
Understanding the behaviours of ice nucleation in non-isothermal conditions is of great importance for the preparation and retention of supercooled water.Here i
【机 构】
:
School of Aeronautics and Astronautics,Shanghai Jiao Tong University,Shanghai 200240,China
论文部分内容阅读
Understanding the behaviours of ice nucleation in non-isothermal conditions is of great importance for the preparation and retention of supercooled water.Here ice nucleation in supercooled water under temperature gradients is analyzed ther-modynamically based on classical nucleation theory (CNT).Given that the free energy barrier for nucleation is dependent on temperature,different from a uniform temperature usually used in CNT,an assumption of linear temperature distribution in the ice nucleus was made and taken into consideration in analysis.The critical radius of the ice nucleus for nucleation and the corresponding nucleation model in the presence of a temperature gradient were obtained.It is observed that the crit-ical radius is determined not only by the degree of supercooling,the only dependence in CNT,but also by the temperature gradient and even the Young's contact angle.Effects of temperature gradient on the change in free energy,critical radius,nucleation barrier and nucleation rate with different contact angles and degrees of supercooling are illustrated successively.The results show that a temperature gradient will increase the nucleation barrier and decrease the nucleation rate,particu-larly in the cases of large contact angle and low degree of supercooling.In addition,there is a critical temperature gradient for a given degree of supercooling and contact angle,at the higher of which the nucleation can be suppressed completely.
其他文献
The crystal-oriented silicon micropillar array platforms were prepared by microfabrication processes for the pur-pose of electrolyte additive identification.Th
We consider the superconducting properties of Lieb lattice,which produces a flat-band energy spectrum in the normal state under the strong electron-electron cor
Morphology control of perovskite films is of critical importance for high-performance photovoltaic devices.Although solvent vapor annealing (SVA) treatment has
Cancer development is a complicated process controlled by the interplay of multiple signaling pathways and restrained by oxygen and nutrient accessibility in the tumor microenvironment.High plasticity in using diverse nutrients to adapt to metabolic stres
We present a scheme of reversible waveform conversion between microwave and optical fields in the hybrid opto-electromechanical system.As an intermediate interf
We investigate the effects of post-sinter annealing on the microstructure and magnetic properties in B-lean Nd-Fe-B sintered magnets with different quantities o
Two-dimensional (2D) transition metal dichalcogenides (TMDCs) such as tungsten diselenide (WSe2) have spead many interesting physical properties,which may becom
RNA viruses cause a multitude of human diseases,including several pandemic events in the past century.Upon viral invasion,the innate immune system responds rapidly and plays a key role in activating the adaptive immune system.In the innate immune system,t
Spectrin,the principal protein of the cytoskeleton of erythrocyte,plays a crucial role in the stability and flexibility of the plasma membrane of erythrocyte.In
Obesity increases the risk of type 2 diabetes through the induction of insulin resistance.The mechanism of insulin resistance has been extensively investigated