烷烃混合物的氧化,例如从石蜡氧化以制取混合脂肪酸,工业上早已进行了研究。以气态烷烃进行氧化,研究氧化反应机理,也有_些报道。但从合成角度,研究从纯粹烷烃制取烷烃氧化衍生物,则文献上尚属少见。在作者的实验室里曾研究了乙氧羰基甲烯对已烷的插入反应。为了考查甲烯是以单线态还是以三线态进行插入,比较了有氧(空气)和无氧存在时对插入产物的影响。结果产物的 The oxidation of alkane mixtures, for example from the oxidation of paraffins to make mixed fatty acids, has long been studied industrially. Oxidation of gaseous alkanes to study the oxidation reaction mechanism, there are some reports. However, from the synthetic point of view, from pure alkane alkane oxidation derivatives, the literature is still rare. In the author’s lab, the insertion of ethoxycarbonylmethane to hexane has been studied. In order to examine whether methylene insertion is in singlet or triplet state, the effect on the insert product in the presence of aerobic (air) and anaerobic was compared. The result of the product