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One new zinc coordination polymer,[Zn(NAA)2(4,4’-bpy)]n(1,HNAA = 1-naphthaleneacetic acid,4,4’-bpy = 4,4’-bipyridine),has been synthesized under hydrothermal conditions and characterized by elemental analysis,IR spectroscopy,thermogravimetric analysis(TGA),and single-crystal X-ray diffraction.Coordination polymer 1 is of monoclinic system,space group Cc with a = 9.8720(6),b = 16.7397(9),c = 17.0371(12) ,β = 104.8080(10)°,V = 2721.9(3)3,C34H26N2O4Zn,Z = 4,Mr = 591.94,Dc = 1.444 g/cm3,μ(MoKα) = 0.946 mm-1,F(000) = 1224,the final R = 0.0282 and wR = 0.0720 for 3300 observed reflections with I > 2σ(I).1 exhibits an interesting one-dimensional chain structure.Furthermore,the luminescent property of 1 has also been investigated.
One new zinc coordination polymer, [Zn (NAA) 2 (4,4’-bpy)] n (1, HNAA = 1-naphthaleneacetic acid, 4,4’-bpy = 4,4’-bipyridine) under hydrothermal conditions and characterized by elemental analysis, IR spectroscopy, thermogravimetric analysis (TGA), and single-crystal X-ray diffraction. Cooperating polymer 1 is a monoclinic system, space group Cc with a = 9.8720 (6), b = 16.7397 (3) 3, C34H26N2O4Zn, Z = 4, Mr = 591.94, Dc = 1.444 g / cm3, μ (MoKα) = 0.946 mm-1, F (000) = 1224, the final R = 0.0282 and wR = 0.0720 for 3300 observed reflections with I> 2σ (I) .1 exhibits an interesting one-dimensional chain structure. has also been investigated