Construction of nickel cobalt sulfide nanosheet arrays on carbon cloth for performance-enhanced supe

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Materials featured with self-supported three-dimensional network,hierarchical pores and rich electrochemical active sites are considered as promising electrodes for pseudocapacitors.Herein,a novel strategy for the growth of nickel-cobalt bisulfide (NiCoS) nanosheets arrays on carbon cloth (CC) as supercapacitor electrodes is reported,involving deposition of two-dimensional metal-organic framework (MOF) precursors on the CC skeletons,conversion of MOF into nickel-cobalt layered double-hydroxide by ion exchange process and formation of NiCoS by a sulfidation treatment.The NiCoS nanosheets with rough surface and porous structures are uniformly anchored on the CC skeletons.The unique architecture endows the composite (NiCoS/CC) with abundant accessible active sites.Besides,robust electrical/mechanical joint between the nanosheets and the substrates is attained,leading to the improved electrochemical performance.Moreover,an asymmetric supercapacitor device is constructed by using NiCoS/CC and activated carbon as a positive electrode and a negative electrode,respectively.The optimized device exhibits a high specific capacitance,large energy density and long cycle life.The NiCoS/CC electrode with intriguing electrochemical properties and mechanical flexibility holds great prospect for next-generation wearable devices.
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