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采用溶剂热法合成了一种新的金属有机配合物[Co2(C8O6H4)2·(H2O)4],通过X射线单晶衍射技术对该化合物进行了结构表征。结果表明,该化合物晶体属三斜晶系,空间群为P1;晶胞参数a=9.389(2)(1=10-10 m),b=9.421(3),c=12.209(3);α=101.846(2)°;β=104.453(2)°;γ=105.305(3)°;V=965.23;Z=2;Dc=2.003g/cm3,μ=1.810mm-1,F(000)=588,GooF=1.044,R1=0.0268,ωR2=0.023 0[I>2σ(I)]。
A new metal-organic complex [Co2 (C8O6H4) 2 · (H2O) 4] was synthesized by solvothermal method. The structure of the compound was characterized by X-ray single crystal diffraction. The results show that the crystal of the compound belongs to the triclinic system with space group P1. The unit cell parameters are a = 9.389 (2) (1 = 10-10 m), b = 9.421 (3) and c = 12.209 Α = 101.846 (2) °; β = 104.453 (2) °; γ = 105.305 (3) °; V = 965.23; Z = 2; Dc = 2.003g / cm3; μ = , F (000) = 588, GooF = 1.044, R1 = 0.0268, ωR2 = 0.023 0 [I> 2σ (I)].