【摘 要】
：
A new cadmium complex Cd(α-FRA)2(Phen)(H2O) was synthesized by self- assembly reaction of α-furoic acid, phenanthroline (phen), and Cd(NO3)2(4H2O. It crystall
【机 构】
：
Department of Chemistry and Materials Science,Department of Chemical Engineering,College of Chemistr
【基金项目】
：
湖南省教育厅资助项目;衡阳师范大学校科研和教改项目;湖南省衡阳科技局资助项目
论文部分内容阅读
A new cadmium complex Cd(α-FRA)2(Phen)(H2O) was synthesized by self- assembly reaction of α-furoic acid, phenanthroline (phen), and Cd(NO3)2(4H2O. It crystallizes in monoclinic, space group P21/c, with a = 0.6799(2), b = 1.7780(6), c = 1.6866(6) nm, β = 94.912(6)o, V = 2.0315(12) nm3, Dc = 1.742 g/cm3, Z = 4, Mr = 532.77, μ(MoKα) = 1.124 mm-1, F(000) = 1064, R = 0.0411, wR = 0.0790. The structural analysis shows that the cadmium ion is coordinated with two nitrogen atoms from one phen molecule and four oxygen atoms respectively from two α-furoic acids and one water molecule, giving a distorted octahedral coordination geometry. The cyclic voltametric behavior of the complex was also discussed, which shows that the electrode process is irreversible in the electrode reactor.
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