In order to lower the raw materials cost and develop a novel cathode materials for intermediate temperature solid oxide fuel cell(ITSOFC), using mixed rare earth replacing the expensive pure La2O3 as the raw materials, the powders of Ln0.7Sr0.3-xCaxCo0.9Fe0.1O3-δ (Ln=the mixed rare earth, x=0.05, 0.10, 0.15) for the applications as the cathode materials were prepared by microwave sintering process. The crystal structure and the particles morphology of the obtained powders were characterized by XRD and SEM, the electrical conductivity of all samples sintered at 1200 ℃ for 3 h was also measured as the function of the temperature from 100 to 800 ℃ by DC four-probe method in air. The experimental results show that due to the influence of mixed rare earth the powders of Ln0.7Sr0.3-xCaxCo0.9Fe0.1O3-δ synthesized at 1200 ℃ for 0.5 h with the mean particle size of 1～20 μm was of perovskite and cubic fluorite phase as well a little SrO phase, the electrical conductivity of the samples decreases with the adding Ca2+ content, and are all higher than 100 S·cm-1 from 500 to 700 ℃ when x≤0.10. Ln0.7Sr0.3-xCaxCo0.9Fe0.1O3-δ. Can meet the demand of the electrical properties for the cathode materials in ITSOFC.