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采用水热法合成了一个一维配位聚合物[Co(H2O)4(bpy)]n(fum)n(4H2O)n1(bpy=4,4’-联吡啶,fum=反丁烯二酸).对其进行了元素分析和X射线单晶衍射测定.该化合物属于单斜晶系,空间群P2(1)/n,晶胞参数a=0.71680(17)nm,b=0.77557(19)nm,c=0.9863(2))nm,α=79.275(2),β=87.808(2),γ=71.294(2)°,z=1,V=0.5101(2)nm3,Dc=1.547g/cm3,F(000)=249,μ=0.905mm-1,R1=0.0298,ωR2=0.0662.
A one-dimensional coordination polymer [Co (H2O) 4 (bpy)] n (fum) n (4H2O) n1 was synthesized by hydrothermal method (bpy = 4,4’-bipyridine, fum = fumaric acid ), And its elemental analysis and X-ray single crystal diffraction were carried out. The compound belongs to the monoclinic space group P2 (1) / n with unit cell parameters of a = 0.71680 (17) nm and b = 0.77557 α = 79.275 (2), β = 87.808 (2), γ = 71.294 (2) °, z = 1, V = 0.5101 (2) nm3 and Dc = 1.547 g / cm3, F (000) = 249, μ = 0.905 mm-1, R1 = 0.0298, ωR2 = 0.0662.