Relocation of the Yellow River estuary has significant impacts on not only terrestrial environment and human activities,but also sedimentary and ecological environments in coastal seas.The responses of regional geochemical characteristics to the relocation event,however,have not been well studied.In the present study,we performed detailed geochemical elemental analyses of a sediment core from the northern Yellow Sea and studied their geochemical responses to the 1855 AD relocation of the Yellow River estuary.The results show that TOC/TN,Co/Al2O3,Cr/Al2O3,Ni/Al2O3and Se/Al2O3ratios all decreased abruptly after 1855 AD,and similar decreases are observed in the sediments of the mud area southwest off the Cheju Island.These abrupt changes are very likely caused by the changes in source materials due to the relocation of the Yellow River estuary from the southern Yellow Sea to the Bohai Sea,which the corresponding decreasing trends caused by the changes in main source materials from those transported by the Liaohe River,the Haihe River and the Luanhe River to those by the Yellow River.Because the events have precise ages recorded in historical archives,these obvious changes in elemental geochemistry of sediments can be used to calibrate age models of related coastal sea sediments. Relocation of the Yellow River estuary has significant impacts on not only terrestrial environment and human activities, but also sedimentary and ecological environments in coastal seas. The responses of regional geochemical characteristics to the relocation event, however, have not been well well.In this present study, we performed detailed geochemical elemental analyzes of a sediment core from the northern Yellow Sea and studied their geochemical responses to the 1855 AD relocation of the Yellow River estuary. The results show that TOC / TN, Co / Al 2 O 3, Cr / Al 2 O 3, Ni / Al2O3 / Se / Al2O3ratios all decreased abruptly after 1855 AD, and more like are observed in the sediments of the mud area southwest off the Cheju Island. These abrupt changes are very likely caused by the changes in source materials due to the relocation of the Yellow River estuary from the southern Yellow Sea to the Bohai Sea, which the corresponding decreased trends caused by the changes in main source materials from that t ransported by the Liaohe River, the Haihe River and the Luanhe River to those by the Yellow River.Because the events have precise ages recorded in historical archives, these obvious changes in elemental geochemistry of sediments can be used calibrate age models of related coastal sea sediments.