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提出一套恒电位脉冲测量暂态电流的技术,通过累加生成处理,可大大降低曲线的噪声,再由非等间距的差分处理,可对电化学体系时间常数作出简便的判定,还分析了脉冲幅度以及溶液电阻的作用,并在Fe/H3BO3+Na2B4O7体系和碳钢/砂土体系中对该方法进行了验证。
A set of techniques for measuring transient current by constant potential pulse is proposed. By accumulating and generating, the noise of the curve can be greatly reduced, and then the time constant of the electrochemical system can be easily judged by the differential processing without equidistance. The pulse Amplitude and solution resistance, and the method was verified in Fe / H3BO3 + Na2B4O7 system and carbon steel / sand system.