【摘 要】
：
The hydrogen storage alloy powders (MlNi4.0Co0.6Al0.4, Ml=rich-La mischmetal) were treated in a hot 6mol/L KOH+0.02mol/L KBH4 solution, the surface compositions
【机 构】
：
Department of Chemistry,Department of Materials Science and Engineering,Department of Physics,State
论文部分内容阅读
The hydrogen storage alloy powders (MlNi4.0Co0.6Al0.4, Ml=rich-La mischmetal) were treated in a hot 6mol/L KOH+0.02mol/L KBH4 solution, the surface compositions and chemical states of the treated and untreated alloys were analyzed by XPS and EDX, the hydrogen adsorption on the surface of these alloys was evaluated by thermal desorption spectroscopy (TDS), the effects of the surface treatment on the electrochemical performances of the alloy electrodes were investigated. The results show that the hydrogen adsorption is greatly strengthened by the surface modification, and hence leads to marked improvement in the electrocatalytic activity, the treated alloy exhibits higher exchange current density and lower apparent activation energy for the hydrogen electrode reaction than the untreated alloy.
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