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首次制得通式为C[Ni(dmid)_2]系列新配位化合物(C为外部阳离子,H_2dmid=4,5-二硫醇-1,3-二硫-2-酮).当这些配合物用化学法氧化时,得到同一种配合物[Ni(dmid)_2],并确定了这些新配合物的组成,研究了它们的IR,UV,ESR,XPS谱和循环伏安图,测定了室温导电率.XPS谱的研究结果说明,用化学法氧化时电子转移过程主要发生在配体上,配位体的电荷分布发生了变化.
For the first time, a series of novel coordination compounds of C [Ni (dmid) _2] family (C is an external cation, H_2dmid = 4,5-dithiol-1,3-dithi-2-one) The same complexes [Ni (dmid) _2] were obtained when the compounds were oxidized by chemical method. The compositions of these new complexes were determined. Their IR, UV, ESR, XPS spectra and cyclic voltammograms were studied. Room temperature conductivity. XPS spectrum results show that the chemical oxidation of the electron transfer process occurs mainly in the ligand, the ligand charge distribution has changed.