Rare earth composite materials radiating far-infrared rays were prepared according to far infrared absorption spectrum of main component in liquefied petroleum gas (LPG). The composite materials were characterized by scanning electron microscope (SEM), X-ray diffraction (XRD), and Fourier transformed infrared spectra(FTIR). The results show that after the composite materials were calcined at 873 K for 4 h, FTIR spectra of rare earth composite materials display two new peaks at 1336 and 2926 cm-1 available for activating LPG.