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在室温下,MnSO4·H2O和1,2,4-苯三甲酸穴H3BTC雪反应得到化合物眼Mn穴H2BTC(2(H2O(4[·2H2O)1(化合物1和CuSO4·5H2O反应得到化合物眼Cu穴HBTC雪穴H2O雪1.5演·H2O穴2雪。化合物1是一个单核分子化合物。在化合物1中熏每个锰离子和两个H2BTC-离子及四个水分子配位。化合物2中熏每个铜离子和三个HBTC2-及两个水分子配位熏其中的一个水分子起桥联作用从而形成二维网状结构。
At room temperature, MnSO4 · H2O and 1,2,4-benzenetricarboxylate H3BTC were reacted to obtain the compound Mn (OH) 2 H2BTC (2 (H2O (4 · 2H2O) 1 by reaction with compound CuSO4 · 5H2O Holes HBTC Snow Holes H2O Snow 1.5 Holes Holes 2 Snow Compound 1 is a mononuclear molecular compound that smokes each manganese ion with two H2BTC- ions and four water molecules in compound 1. Compound 2 smoked Each copper ion and three HBTC2- and two water molecules coordinate smoked one of the water molecules play a role in bridging to form a two-dimensional network structure.